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This article is about crystalline solids. This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i. Despite the name, lead crystal, crystal glass, and related products are not crystals, but rather types of glass, i.
Microscopic structure of a halite crystal. The scientific definition of a “crystal” is based on the microscopic arrangement of atoms inside it, called the crystal structure. A crystal is a solid where the atoms form a periodic arrangement. For example, when liquid water starts freezing, the phase change begins with small ice crystals that grow until they fuse, forming a polycrystalline structure. The unit cells are stacked in three-dimensional space to form the crystal. The symmetry of a crystal is constrained by the requirement that the unit cells stack perfectly with no gaps.
As a halite crystal is growing, new atoms can very easily attach to the parts of the surface with rough atomic-scale structure and many dangling bonds. Crystals are commonly recognized, macroscopically, by their shape, consisting of flat faces with sharp angles. These shape characteristics are not necessary for a crystal—a crystal is scientifically defined by its microscopic atomic arrangement, not its macroscopic shape—but the characteristic macroscopic shape is often present and easy to see. Euhedral crystals are those that have obvious, well-formed flat faces. Anhedral crystals do not, usually because the crystal is one grain in a polycrystalline solid.
One of the oldest techniques in the science of crystallography consists of measuring the three-dimensional orientations of the faces of a crystal, and using them to infer the underlying crystal symmetry. A crystal’s crystallographic forms are sets of possible faces of the crystal that are related by one of the symmetries of the crystal. For example, crystals of galena often take the shape of cubes, and the six faces of the cube belong to a crystallographic form that displays one of the symmetries of the isometric crystal system. Forms may be closed, meaning that the form can completely enclose a volume of space, or open, meaning that it cannot.